Crystal Structure of Octahedral Coordinated Trinuclear Cu(II) Complex 1,1,1-Tris(N-salicylideneaminomethyl)ethane
نویسندگان
چکیده
منابع مشابه
SYNTHESIS, X-RAY CRYSTAL STRUCTURE AND IR STUDY OF NEW TRINUCLEAR, BASE CARBOXSYLATE COMPLEX OF [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O
The synthesis of [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O is described. The X-ray crystallographic study of thecomplex revealed an isosceles triangle of copper atoms with a triply bridging oxo atom nearly in the plane of thetriangle. The coordination sphere around each metal center is close to distorted octahedral and the central{Cu3(μ3-O)} core is planar. Every two copper atoms were connected to each o...
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[Ni3(C2H3 0 2 )2(CH3 0 H)2L2] [L = l,3-bis(5-chlorosalicylideneamino)propan-2-ol dianion, (C2H3 0 2 )_ = acetate, (CH3OH) = methanol] was synthesized and its crystal structure was determined. It crystallizes in the monoclinic spaceeroup P2i /n with a = 12.694(2), b = 13.281 (4), c = 15.420(3) Ä, ß = 111.25(2)°, V = 2422.9(9) A ? ,Z = 2 . The molecule is a “linear” trinuclear complex with nearly...
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To calculation non-bonded interaction of the [CoCl6]3- complex embedded in nano ring, we focus on the single wall boron-nitride B18N18 nano ring. Thus, the geometry of B18N18 nano ring has been optimized by B3LYP method with EPR-II (Electron paramagnetic resonance) basis set and geometry of the [CoCl6]3- complex has been optimized at B3LYP method with Aldrich’s VTZ basis set and Stuttgart RSC 1...
متن کاملElectronic Structure Investigation of Octahedral Complex and Nano ring by NBO Analysis: An EPR Study
To calculation non-bonded interaction of the [CoCl6]3- complex embedded in nano ring, we focus on the single wall boron-nitride B18N18 nano ring. Thus, the geometry of B18N18 nano ring has been optimized by B3LYP method with EPR-II (Electron paramagnetic resonance) basis set and geometry of the [CoCl6]3- complex has been optimized at B3LYP method with Aldrich’s VTZ basis set and Stuttgart RSC 1...
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ژورنال
عنوان ژورنال: X-ray Structure Analysis Online
سال: 2010
ISSN: 1883-3578
DOI: 10.2116/xraystruct.26.37